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Rhenium-Catalyzed Addition of Trimethylsilylacetylene to Aldimines.

✍ Scribed by Yoichiro Kuninobu; Yuichi Inoue; Kazuhiko Takai

Book ID
102007807
Publisher
John Wiley and Sons
Year
2007
Weight
23 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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Rh(I)-catalyzed addition of alkenylzirco
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✍ Akito Kakuuchi; Takeo Taguchi; Yuji Hanzawa πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 139 KB

RhCl(COD)] 2 (2 mol%) catalyzed reactions of alkenylzirconocene chloride complexes to N-Ts, -PO(OEt) 2 and COOR aldimine derivatives were efficiently carried out in dioxane at room temperature to give allylic amine derivatives in excellent yields. This is the first example of the catalytic addition