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Rh(I)-catalyzed addition of alkenylzirconocene chlorides to aldimine derivatives

โœ Scribed by Akito Kakuuchi; Takeo Taguchi; Yuji Hanzawa

Book ID
104252838
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
139 KB
Volume
44
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

RhCl(COD)] 2 (2 mol%) catalyzed reactions of alkenylzirconocene chloride complexes to N-Ts, -PO(OEt) 2 and COOR aldimine derivatives were efficiently carried out in dioxane at room temperature to give allylic amine derivatives in excellent yields. This is the first example of the catalytic addition reactions of alkenylzirconocene chloride complexes to aldimine derivatives.

๐Ÿ“œ SIMILAR VOLUMES

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Rh(I)-Catalyzed Conjugate Addition of Alkenylzirconocene Chloride: Stereoselective Formation of Carbocycles Through Cascade Reaction.
โœ Yuji Hanzawa; Yoshitaka Takebe; Akio Saito; Akito Kakuuchi; Haruhiko Fukaya ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› John Wiley and Sons โš– 37 KB ๐Ÿ‘ 1 views

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