In the previous papers, 1,2) we proposed the structures of coriolin, coriolin B and C based on spectroscopic analysis, biogenetic consideration and chemical transformations. We should revise these structures based on new evidences. In this paper we report the structures and stereochemistry as pres
✦ LIBER ✦
Revised structure and stereochemistry of jatamansic acid
✍ Scribed by Gerhard Rücker; Shashikumar Keshav Paknikar; Ralf Mayer; Eberhard Breitmaier; Georg Will; Leonore Wiehl
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 238 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0031-9422
No coin nor oath required. For personal study only.
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## Abstract For Abstract see ChemInform Abstract in Full Text.
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A stereoselective total synthesis of the proposed structure of kaitocephalin (1) was accomplished starting from L-proline and D-and L-serines. However, its 1 H NMR spectral data and retention time on HPLC were not identical with those of authentic natural kaitocephalin. The revised stereochemistry o