In the previous papers, 1,2) we proposed the structures of coriolin, coriolin B and C based on spectroscopic analysis, biogenetic consideration and chemical transformations. We should revise these structures based on new evidences. In this paper we report the structures and stereochemistry as pres
β¦ LIBER β¦
Revised structure and stereochemistry of chrysartemin B
β Scribed by Toshihiko Osawa; Donald Taylor; Akinori Suzuki; Saburo Tamura
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- French
- Weight
- 162 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0040-4039
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A stereoselective total synthesis of the proposed structure of kaitocephalin (1) was accomplished starting from L-proline and D-and L-serines. However, its 1 H NMR spectral data and retention time on HPLC were not identical with those of authentic natural kaitocephalin. The revised stereochemistry o