Revised Structure and Stereochemistry of Coriolins
β Scribed by Shuji Takahashi; Hiroshi Naganawa; Hironobu Iinuma; Tomohisa Takita; Kenji Maeda; Hamao Umezawa
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 203 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
In the previous papers, 1,2) we proposed the structures of coriolin, coriolin B and C based on spectroscopic analysis, biogenetic consideration and chemical transformations.
We should revise these structures based on new evidences.
In this paper we report the structures and stereochemistry as presented in I, II and III.
π SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
A stereoselective total synthesis of the proposed structure of kaitocephalin (1) was accomplished starting from L-proline and D-and L-serines. However, its 1 H NMR spectral data and retention time on HPLC were not identical with those of authentic natural kaitocephalin. The revised stereochemistry o