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Reversible Topochemical Transformation of a Soft Crystal of a Coordination Polymer

✍ Scribed by Sujit K. Ghosh; Jie-Peng Zhang; Susumu Kitagawa


Book ID
102728987
Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
638 KB
Volume
46
Category
Article
ISSN
0044-8249

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Reversible Mechanochemistry of a PdII Co
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Ultrasound-induced chain scission in dissolved Pd II coordination polymers is highly selective for the dissociation of phosphane ligands from palladium and therefore reversible. The original molecular weight of the polymer is restored after sonication. See the Communication by J. M.