Reversible Mechanochemistry of a PdII Coordination Polymer

✍ Scribed by Jos M. J. Paulusse; Rint P. Sijbesma

• Book ID: 101568491
• Publisher: John Wiley and Sons
• Year: 2004
• Tongue: English
• Weight: 248 KB
• Volume: 43
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.200460040

✦ Synopsis

Ultrasound-induced chain scission in dissolved Pd II coordination polymers is highly selective for the dissociation of phosphane ligands from palladium and therefore reversible. The original molecular weight of the polymer is restored after sonication. See the Communication by J. M.