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Reversible Mechanochemistry of a PdII Coordination Polymer

✍ Scribed by Jos M. J. Paulusse; Rint P. Sijbesma


Book ID
101533100
Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
248 KB
Volume
116
Category
Article
ISSN
0044-8249

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Reversible Mechanochemistry of a PdII Co
✍ Jos M. J. Paulusse; Rint P. Sijbesma πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 248 KB

Ultrasound-induced chain scission in dissolved Pd II coordination polymers is highly selective for the dissociation of phosphane ligands from palladium and therefore reversible. The original molecular weight of the polymer is restored after sonication. See the Communication by J. M.