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Reversible Opening of a Trinuclear Heterometal Cluster

✍ Scribed by Prof. Dr. Gottfried Huttner; Josef Schneider; Dr. Hans-Dieter Müller; Dr. Gerhard Mohr; Dipl.-Chem. Joachim von Seyerl; Lidwina Wohlfahrt


Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
250 KB
Volume
18
Category
Article
ISSN
0044-8249

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## Abstract A new linear chain complex of oxo‐centered trinuclear manganese clusters, [{Mn^III^~2~Mn^II^O(O~2~CCHCl~2~)~6~(H~2~O)}{Mn(O~2~CCHCl~2~)~2~(H~2~O)~4~}]~__n__~ (1), has been synthesized by treatment of a mixture of Mn(OAc)~2~·4H~2~O and dichloroacetic acid in dichloromethane with KMnO~4~.