𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A Novel One-Dimensional Chain Complex Composed of Oxo-Centered Trinuclear Manganese Clusters

✍ Scribed by Jinkwon Kim; Jin Mook Lim; Youngkyu Do

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
117 KB
Volume
2003
Category
Article
ISSN
1434-1948

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

A new linear chain complex of oxo‐centered trinuclear manganese clusters, [{Mn^III^~2~Mn^II^O(O~2~CCHCl~2~)~6~(H~2~O)}{Mn(O~2~CCHCl~2~)~2~(H~2~O)~4~}]~n~ (1), has been synthesized by treatment of a mixture of Mn(OAc)~2~·4H~2~O and dichloroacetic acid in dichloromethane with KMnO~4~. In this complex chains are formed by hydrogen bonding between carboxylate oxygens and coordinated water molecules, forming a two‐dimensional structure. Antiferromagnetic coupling was observed by variable‐temperature magnetic measurements. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

📜 SIMILAR VOLUMES

[NbAs8]3−, a Novel Type of Complex and a
[NbAs8]3−, a Novel Type of Complex and an Unexpected One-Dimensional Chain Structure: [Rb{NbAs8}]2−
✍ Prof. Dr. Hans-Georg von Schnering; Dipl.-Chem. Juliana Wolf; Dr. Dieter Weber; 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 252 KB 👁 1 views

which would be in agreement with the (irregular) increase in the differences A6=16(x)-6(x+ 1)1 in the series [P7 -x A ~x ] 3 ~ with increasing x. It is also possible, however, that this heteroanion is unstable and decomposes into As: -and, for example, [P2Ass]37, because incorporation of the small P

ChemInform Abstract: Hydrothermal Synthe
ChemInform Abstract: Hydrothermal Synthesis, Structure Characterization and Catalytic Property of a Zigzag Chain Structural Cluster Compound Built on the Novel Tetra-Capped and Centered By NiII.
✍ Dawei Yan; Qi Chen; Yan Xu; Qi Sun; Dunru Zhu; You Song; S. P. Elangovan 📂 Article 📅 2012 🏛 John Wiley and Sons ⚖ 28 KB 👁 1 views

## Abstract The novel Mo/W mixed Keggin derivative (IV) is characterized by powder and single crystal XRD, XPS, IR spectroscopy, and magnetic susceptibility measurements.