Reversibility Relationship in Collision-Complex-Forming Bimolecular Reactions
โ Scribed by Smith, Sean C.; McEwan, Murray J.; Brauman, John I.
- Book ID
- 127173222
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 106 KB
- Volume
- 101
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
A formulation of the theory for diffusion influenced reversible reaction A+BX in solution is used to study the effect of the back reaction on the bimolecular forward rate coefficient. The formula recently derived by Szabo that relates the forward rate coefficient in the presence of the back reaction
The exprcrsions for the obserred rate const.mrs of the forpart? bimoleculx .md back monomolecuhr reactions have been obtained using the boundary conditions imposed upon the reaction surfxes of each reagent particIe. The rate, equilibrium and thermodynamical pzu-ameters of the back dibsocutron reacti