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Detailed equilibrium principle in reversible bimolecular diffusion-controlled reactions

✍ Scribed by S.F. Burlatsky; P.P. Levin; I.V. Khudyakov; V.A. Kuzmin; A.A. Ovchinnikov


Book ID
103017225
Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
429 KB
Volume
66
Category
Article
ISSN
0009-2614

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✦ Synopsis


The exprcrsions for the obserred rate const.mrs of the forpart? bimoleculx .md back monomolecuhr reactions have been obtained using the boundary conditions imposed upon the reaction surfxes of each reagent particIe. The rate, equilibrium and thermodynamical pzu-ameters of the back dibsocutron reactions of pheno\_v radical dimers hate been measured-The resultant flues of.Pp .ts 'J function of solrent liscosit) are accumtcl) described b> theoretica relationships obtained in the pre>ent xkork.


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S~~~YIUI~ from the generalized theory of blmolwlar diffusion-controlled reactiorus betwatn reagents in soli& and liquids, we have performed calculations of Lhe A+B \* AB (F'renkel defecL anmhilalion) and A+A + B (exciton annihdation) reaction kinetics over a wide time interval and for high initial c