S~~~YIUI~ from the generalized theory of blmolwlar diffusion-controlled reactiorus betwatn reagents in soli& and liquids, we have performed calculations of Lhe A+B \* AB (F'renkel defecL anmhilalion) and A+A + B (exciton annihdation) reaction kinetics over a wide time interval and for high initial c
β¦ LIBER β¦
Detailed equilibrium principle in reversible bimolecular diffusion-controlled reactions
β Scribed by S.F. Burlatsky; P.P. Levin; I.V. Khudyakov; V.A. Kuzmin; A.A. Ovchinnikov
- Book ID
- 103017225
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 429 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
The exprcrsions for the obserred rate const.mrs of the forpart? bimoleculx .md back monomolecuhr reactions have been obtained using the boundary conditions imposed upon the reaction surfxes of each reagent particIe. The rate, equilibrium and thermodynamical pzu-ameters of the back dibsocutron reactions of pheno\_v radical dimers hate been measured-The resultant flues of.Pp .ts 'J function of solrent liscosit) are accumtcl) described b> theoretica relationships obtained in the pre>ent xkork.
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