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Reversed Stereoselectivity in Iodohydroxylation of Allenyl Sulfides. An Efficient Synthesis of (Z)-3-Organosulfur-2-iodo-2-propenols.

✍ Scribed by Shengming Ma; Xueshi Hao; Xian Huang


Publisher
John Wiley and Sons
Year
2003
Weight
110 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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## Abstract An efficient protocol for the highly regio‐ and stereoselective synthesis of 4‐(3′‐hydroxy‐2′‐iodoalk‐1β€²(__Z__)‐enyl)furan‐2(5__H__)‐one derivatives __via__ selective iodohydroxylation of non‐heteroatom‐substituted allenes, i.e., 4‐allenyl‐2(5__H__)furanones, has been developed. The reg