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Reversal of stereochemistry in diethylzinc addition to aldehydes by a simple change of the backbone substituent in L-serine derived ligands

✍ Scribed by Mukund P. Sibi; Jian-xie Chen; Gregory R. Cook

Book ID: 104261265
Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 255 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)00480-3

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✦ Synopsis

A change in the backbone substituent from phenyl to butyl group in L-serine-derived ligands provides a simple way to prepare enantiomefic products in diethylzinc addition to aldehydes.

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