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Restricted conformational processes in 10,11-dihydro-5h-dibenz [b,f]azepine erivatives. a DNMR study

✍ Scribed by G. Bellucci; R. Bianchini; C. Chiappe; F. Marioni; D. Catalano


Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
447 KB
Volume
44
Category
Article
ISSN
0040-4020

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The stereoselectivity of the reduction of 5-carbamoyl-l0, I 1-dihydro-1 l-oxo-SH-dibenz[bflazepine-lO-yl acetate (6), prepared in two steps from 10, I l-dihydro-lO-oxo-5H-dibenz[hflazepine-5-carboxamide (4), has been studied. Among the reagents used, diisobutylaluminum hydride (DIBAH) was found to g