Resonances in the photodissociation of CO2: periodic-orbit and wavepacket analyses
β Scribed by Irene Burghardt; Pierre Gaspard
- Book ID
- 108430628
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 680 KB
- Volume
- 225
- Category
- Article
- ISSN
- 0301-0104
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π SIMILAR VOLUMES
We discuss the origin of reactive scattering resonances in absorption cross sections following the collinear photodissociation of symmetric triatomic molecules. The analysis of spectra for CO, dissociation, previously calculated by Kulander and Light, becomes very simple in terms of polar coordinate
A hybrid quantum/semiclassical simulation method is applied to the photodissociation dynamics of HCI in the Ar-HCI cluster. The method treats the hydrogen quantum mechanically, and the heavy atoms by semiclassical wavepackets. The dynamics of the H atoms if found to show resonances where the H atom