The photodissociation of CH2BrCl at 248 and 193 nm has been studied by translational spectroscopy. Both the product translational energy distribution and the anisotropy parameter were derived from the measured time-of-flight spectra. Results show that at 248 nm, CHzBrCl exclusively dissociates to CH
Dynamics of CO formation in the photodissociation of HNCO and CH2CO at 193nm
โ Scribed by G.T. Fujimoto; M.E. Umstead; M.C. Lin
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 594 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0301-0104
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An analysis of the primary photodissociation products resulting fro-m the 193 nm photolysis of HSCO is reported\_ The major fngments are NH(a IA, u' = 0) and CO(X '~3. Reaction of NH(a 'A) with 02 and with HIiCO produces only nonemissive products. A rapid E-E, V energy transfer occurs for collisions
Photodissociation of H$ has been studied at 193.3 nm using H atom photofragment-translational speclroscopy with massspectrometric detection. H t HS( v) product branching ratios are reported which are not in quantitative agreement with other recent experimental results. Secondary photodissociation of