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Reactive resonances in the photodissociation of symmetric triatomic molecules: an interpretation of collinear CO2 in terms of polar coordinates

✍ Scribed by Reinhard Schinke; Volker Engel


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
488 KB
Volume
124
Category
Article
ISSN
0009-2614

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✦ Synopsis


We discuss the origin of reactive scattering resonances in absorption cross sections following the collinear photodissociation of symmetric triatomic molecules. The analysis of spectra for CO, dissociation, previously calculated by Kulander and Light, becomes very simple in terms of polar coordinates. Of particular interest is a symmetry effect which is not observable m ordinary scattering calculations.