Resonance Raman spectra of the ground and excited states of specifically deuterated tris(2,2'-bipyridine)ruthenium(II)
β Scribed by McClanahan, Stephen; Hayes, Thomas; Kincaid, James
- Book ID
- 126324002
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 263 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The existence of two independent chromophores in [Ru(bipy)~2~(H~2~V)]^+^, where H~2~V^β^ = violurate anion and bipy = 2,2β²bipyridine, was demonstrated by comparing its resonance Raman spectra with those displayed by the [Ru(H~2~V)~3~]^β^ analogue. In the former, the electronic band at 4
Resonance enhanced Raman spectra are reported for the complexes M(bpy-d&"[M = Fe(II), Ru(II)] and Ru(bpy-d8),C12, where bpy-ds is perdeuteriated 2,2'-bipyridine. Correlations are made with the corresponding resonance enhanced modes of the hydrogen containing compounds for the spectra obtained in res