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Resonance Raman spectra of ruthenium(II) complexes of bipyridine and substituted bipyridines: ground- and excited-state properties

✍ Scribed by Basu, Amitabha.; Gafney, Harry D.; Strekas, Thomas C.

Book ID: 125897135
Publisher: American Chemical Society
Year: 1982
Tongue: English
Weight: 651 KB
Volume: 21
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic00136a021

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## Abstract The existence of two independent chromophores in [Ru(bipy)~2~(H~2~V)]^+^, where H~2~V^−^ = violurate anion and bipy = 2,2′bipyridine, was demonstrated by comparing its resonance Raman spectra with those displayed by the [Ru(H~2~V)~3~]^−^ analogue. In the former, the electronic band at 4