## Abstract The existence of two independent chromophores in [Ru(bipy)~2~(H~2~V)]^+^, where H~2~V^−^ = violurate anion and bipy = 2,2′bipyridine, was demonstrated by comparing its resonance Raman spectra with those displayed by the [Ru(H~2~V)~3~]^−^ analogue. In the former, the electronic band at 4
Resonance Raman spectra of iron(II) and ruthenium(II) complexes with perdeuteriated 2,2′-bipyridine
✍ Scribed by Thomas C. Strekas; Santosh K. Mandal
- Publisher
- John Wiley and Sons
- Year
- 1984
- Tongue
- English
- Weight
- 340 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0377-0486
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✦ Synopsis
Resonance enhanced Raman spectra are reported for the complexes M(bpy-d&"[M = Fe(II), Ru(II)] and Ru(bpy-d8),C12, where bpy-ds is perdeuteriated 2,2'-bipyridine. Correlations are made with the corresponding resonance enhanced modes of the hydrogen containing compounds for the spectra obtained in resonance with the visible metal to ligand charge-transfer (MLCT) absorption bands. In particular, the effect of in-plane C-H(D) deformation modes on the resonance active vibrations is discussed.
📜 SIMILAR VOLUMES
The temperature dependence of the emission lifetime of the series of complexes Ru(bpy),(4,4'-dpb): ? (bpy = 2,2'-bipyridine, 4,4'-dpb = 4,4'-diphenyL2,2'-bipyridine) has been studied in propionitrile/butyronitrile (4:5 u/u) solutions in the range 90-293 K. The obtained photophysical parameters show