𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Resonance Raman spectra of iron(II) and ruthenium(II) complexes with perdeuteriated 2,2′-bipyridine

✍ Scribed by Thomas C. Strekas; Santosh K. Mandal


Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
340 KB
Volume
15
Category
Article
ISSN
0377-0486

No coin nor oath required. For personal study only.

✦ Synopsis


Resonance enhanced Raman spectra are reported for the complexes M(bpy-d&"[M = Fe(II), Ru(II)] and Ru(bpy-d8),C12, where bpy-ds is perdeuteriated 2,2'-bipyridine. Correlations are made with the corresponding resonance enhanced modes of the hydrogen containing compounds for the spectra obtained in resonance with the visible metal to ligand charge-transfer (MLCT) absorption bands. In particular, the effect of in-plane C-H(D) deformation modes on the resonance active vibrations is discussed.


📜 SIMILAR VOLUMES


Resonance Raman spectra of tris(violurat
✍ V. R. L. Constantino; H. E. Toma; L. F. C. de Oliveira; P. S. Santos 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 312 KB

## Abstract The existence of two independent chromophores in [Ru(bipy)~2~(H~2~V)]^+^, where H~2~V^−^ = violurate anion and bipy = 2,2′bipyridine, was demonstrated by comparing its resonance Raman spectra with those displayed by the [Ru(H~2~V)~3~]^−^ analogue. In the former, the electronic band at 4

Photophysical Properties and Photochemic
✍ Luisa De Cola; Franceso Barigelletti; Michael J. Cook 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 German ⚖ 464 KB 👁 1 views

The temperature dependence of the emission lifetime of the series of complexes Ru(bpy),(4,4'-dpb): ? (bpy = 2,2'-bipyridine, 4,4'-dpb = 4,4'-diphenyL2,2'-bipyridine) has been studied in propionitrile/butyronitrile (4:5 u/u) solutions in the range 90-293 K. The obtained photophysical parameters show