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Resonance Raman spectra and excitation profiles of the mixed valence compound wolffram's red [PtII(C2H5NH2)4][PtIV(C2H5NH2)4Cl2]Cl44H2O

✍ Scribed by R.J.H. Clark; M.L. Franks; W.R. Trumble

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 582 KB
Volume: 41
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)80812-3

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✦ Synopsis

The resonance Raman spectrum of Wolffram's red is characterized by a progression in IQ, the Cl-dv-CJ symmetric breathing fundamental, tvhich reaches 9vr ; WI and x1 1 are found to be 319.5 and -2.00 cm-r respectively. The excitation profiles of VI and 2vt (both Stokes) and z~r (anti-Stokes) maximite at approximately ore (17 700 cm-'), v20 (17 950 cm-'), and uol (17 200 cm-') respectively, VM) being the 17 450 cm-l axially polarized mixed-vdence transition.

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