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Resonance raman excitation profiles for the totally symmetric mode of the permanganate ion

✍ Scribed by Robin J.H. Clark; David G. Cobbold; Brian Stewart

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
228 KB
Volume
69
Category
Article
ISSN
0009-2614

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✦ Synopsis

Resonance Raman evcltatlon profiles of the vl(al), 2q and 3~~ bands of the [hInO4]-ion doped in K]ClO4] have been measured throughout the entue range of the vibromcally structured 'Tz -'Al (2e -t 1) absorptron band. The profiles dlsplay clear ribrome structure. The profiles of the overtones and the fundamental cross and recross one-other Both these

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Exact and adiabatic treatments of resonance Raman excitation profiles of vibronically active totally symmetric modes are compared. It is shown that an extension of the adiabatic treatment beyond linear non-Condon terms is necessary for situations where the interacting electronic states have very dif