Resonance Raman evcltatlon profiles of the vl(al), 2q and 3~~ bands of the [hInO4]-ion doped in K]ClO4] have been measured throughout the entue range of the vibromcally structured 'Tz -'Al (2e -t 1) absorptron band. The profiles dlsplay clear ribrome structure. The profiles of the overtones and the
Resonance raman excitation profile for the 848 cm−1 totally symmetric mode of the chromate ion
✍ Scribed by E. Campani; F. Ferri; G. Gorini; E. Polacco; G. Masetti
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 419 KB
- Volume
- 107
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
By using CL pulsed dye laser, a detailed Rsman excitation profile for the q(A,) mode of CrOf-in aqueous solution was measured throughout the 'T, .-' Al transition at 371 nm. The Rxnan profile showed a shoulder around 383 nm which was tentatively assigned to B vibronic structure.
📜 SIMILAR VOLUMES
Resonance Raman specna have been measured 81 = 20 K Ior a variety or excitation wavelengths within the IT2 t 'A, (2e + I,) visible absorption band or Lhe [ReS.,]-ion. Excilalion imo vibronic sidebands associated with non-lomlly-symmeh-ic f&e origins results in seleaive enhancement of the appropriate