Resolution of N-acyl-1-naphthylalkylamide on amide and sulfonamide-derived π-acidic chiral stationary phases
✍ Scribed by Jae Jeong Ryoo; Kyu Sung Heo; Young Ae Song
- Book ID
- 108360700
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 134 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0026-265X
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A chiral stationary phase (CSP 2) was prepared by connecting N-(3,5-dinitrobenzoyl)-(R)-phenylglycinol to silica gel through carbamate linkage. The CSP was applied in resolving racemic N-acyl-1-arylaminoalkanes and the chromatographic resolution results were compared with those on the previously rep
## Abstract The liquid chromatographic enantiomer separation of __N__‐fluorenylmethoxycarbonyl (FMOC) protected α‐amino acids and their ethyl ester derivatives was performed on polysaccharide‐derived chiral stationary phases, Chiralcel OD, Chiralpak AD, and Chiralpak AS. In general, Chiralcel OD an