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Resolution of ketones via chiral acetals. Kinetic approach

✍ Scribed by Mori, Atsunori; Yamamoto, Hisashi


Book ID
120178214
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
350 KB
Volume
50
Category
Article
ISSN
0022-3263

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Kinetic Resolution of Racemic Cyclic Olefins via Chiral Dioxirane. -The highly enantioselective epoxidation of 1,3-and 1,6-disubstituted cyclohexenes with Oxone as oxidant and a fructose-derived ketone as catalyst is used for the kinetic resolution of these compounds, which are usually obtained wit