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ChemInform Abstract: Kinetic Resolution of Racemic Cyclic Olefins via Chiral Dioxirane.

✍ Scribed by Michael Frohn; Xiaoming Zhou; Jian-Rong Zhang; Yong Tang; Yian Shi

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Kinetic Resolution of Racemic Cyclic Olefins via Chiral Dioxirane.

-The highly enantioselective epoxidation of 1,3-and 1,6-disubstituted cyclohexenes with Oxone as oxidant and a fructose-derived ketone as catalyst is used for the kinetic resolution of these compounds, which are usually obtained with ΒΏ90% enantiomeric excesses. -(FROHN,

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