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Resolution and absolute configuration of an organopalladium(II) complex

✍ Scribed by R. Claverini; A. De Renzi; P. Ganis; A. Panunzi; C. Pedone


Book ID
108354288
Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
206 KB
Volume
51
Category
Article
ISSN
0022-328X

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Resolution and absolute configuration of
✍ William L. Waters; Marjorie C. Caserio πŸ“‚ Article πŸ“… 1968 πŸ› Elsevier Science 🌐 French βš– 187 KB

We wish to report a simple one-step method for the partial resolution of racemic allenes based on the procedure of asymmetric hydroboration developed by H. C. Brown and coworkers('). Hydroboration of (-)-a-pinene in diglyme leads to (+)-sym-tetraisopinocampheyldiborane (lb) , I, which has been show