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Requirements for Selective Hydrophobic Acceleration in the Reduction of Ketones

✍ Scribed by Biscoe, Mark R.; Uyeda, Christopher; Breslow, Ronald

Book ID
118116883
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
71 KB
Volume
6
Category
Article
ISSN
1523-7060

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πŸ“œ SIMILAR VOLUMES

A convenient one-pot procedure for the s
A convenient one-pot procedure for the selective reduction of ketones in the presence of aldehydes
✍ Mario Paglialunga Paradisi; Giampiero Pagani Zecchini; Giorgio Ortar πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 French βš– 212 KB

The title process has been accomplished by a three-step sequence involving protection of aldeh;de as the imine, in situ reduction of ketone with lithium tri-tert-butoxyaluminohydride, and regeneration of aldehyde on hydrolytic work-up. The preferential in situ ketalization or hydration of aldehydes

Enantioselective reduction of ketones in
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✍ Fumio Toda; Tatsuya Shigemasa πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 English βš– 173 KB

Few enantioselective reductions of ketones in inclusion complexes with cyclomaltoheptaose (p-cyclodextrin, /3CD) have been reported. Sakuraba et aE.l noted that treatment of such complexes with NaBH, in aqueous NaCl at 0" gave optically active alcohols, although the optical purity was not high. Dur