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A general method for the selective reduction of ketones in the presence of enones.

โœ Scribed by Dale E. Ward; Chung K. Rhee; Wajdi M. Zoghaib

Book ID
108381594
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
228 KB
Volume
29
Category
Article
ISSN
0040-4039

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A convenient one-pot procedure for the s
A convenient one-pot procedure for the selective reduction of ketones in the presence of aldehydes
โœ Mario Paglialunga Paradisi; Giampiero Pagani Zecchini; Giorgio Ortar ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 212 KB

The title process has been accomplished by a three-step sequence involving protection of aldeh;de as the imine, in situ reduction of ketone with lithium tri-tert-butoxyaluminohydride, and regeneration of aldehyde on hydrolytic work-up. The preferential in situ ketalization or hydration of aldehydes