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Selective reduction of aldehydes in the presence of ketones

โœ Scribed by Risbood, Prabhakar A.; Ruthven, Douglas M.


Book ID
126120570
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
311 KB
Volume
44
Category
Article
ISSN
0022-3263

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โœ Mario Paglialunga Paradisi; Giampiero Pagani Zecchini; Giorgio Ortar ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 212 KB

The title process has been accomplished by a three-step sequence involving protection of aldeh;de as the imine, in situ reduction of ketone with lithium tri-tert-butoxyaluminohydride, and regeneration of aldehyde on hydrolytic work-up. The preferential in situ ketalization or hydration of aldehydes