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Remote Substituent Effects on Homolytic Bond Dissociation Energies

✍ Scribed by Fu, Yao; Liu, Lei; Lin, ; Mou, Yi; Cheng, Yu-Hui; Guo, Qing-Xiang


Book ID
127013082
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
151 KB
Volume
68
Category
Article
ISSN
0022-3263

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Substituent Effects on the Bond-Dissocia
✍ Katrin Schroeter; Ralf Wesendrup; Helmut Schwarz πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 508 KB

The bond-dissociation energies (BDEs) of more than twenty areneΟͺM + complexes (M = Cr, Fe, Co) have been studied by mass spectrometry, using the kinetic method. With minor exceptions, the same relative order of BDEs is found for the three metals and the series of substituted arenes: electrondonating