𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Remote Substituent Effects on Allylic and Benzylic Bond Dissociation Energies. Effects on Stabilization of Parent Molecules and Radicals

✍ Scribed by Zavitsas, Andreas A.; Rogers, Donald W.; Matsunaga, Nikita

Book ID
127088037
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
208 KB
Volume
72
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Reactions of Alkyl Radicals with Substit
Reactions of Alkyl Radicals with Substituted Toluenes and the Effect of Substituents on Dissociation Energies of Benzyl CH Bonds
✍ Abdelfattah M. Arafat; Samuel K. Mathew; Solademi O. Akintobi; Andreas A. Zavits 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 German ⚖ 141 KB 👁 1 views

## Abstract Reactions of isopropyl and of undecyl radicals with __meta‐__ and __para__‐substituted toluenes are reported. The results demonstrate that the reactivities of toluenes are due to both benzyl‐H abstraction and addition of the alkyl radicals to the aromatic ring. Relative reactivities yie

Substituent Effects on the Bond-Dissocia
Substituent Effects on the Bond-Dissociation Energies of Cationic Arene−Transition-Metal Complexes
✍ Katrin Schroeter; Ralf Wesendrup; Helmut Schwarz 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 508 KB

The bond-dissociation energies (BDEs) of more than twenty areneϪM + complexes (M = Cr, Fe, Co) have been studied by mass spectrometry, using the kinetic method. With minor exceptions, the same relative order of BDEs is found for the three metals and the series of substituted arenes: electrondonating