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Substituent Effects on the Bond-Dissociation Energies of Cationic Arene−Transition-Metal Complexes

✍ Scribed by Katrin Schroeter; Ralf Wesendrup; Helmut Schwarz

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
508 KB
Volume
1998
Category
Article
ISSN
1434-193X

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✦ Synopsis

The bond-dissociation energies (BDEs) of more than twenty areneϪM + complexes (M = Cr, Fe, Co) have been studied by mass spectrometry, using the kinetic method. With minor exceptions, the same relative order of BDEs is found for the three metals and the series of substituted arenes: electrondonating substituents, like alkyl or amino groups, increase the areneϪmetal BDE whereas electron-withdrawing substi-

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