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Remote substituent effect on the regioselectivity in the baeyer-villiger oxidation of 5α-cholestan-6-one derivatives

✍ Scribed by Suguru Takatsuto; Nobuo Ikekawa


Book ID
108381855
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
210 KB
Volume
24
Category
Article
ISSN
0040-4039

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2,3-and 2,5-Dicyanobenzobarrelenes 5 and 6 have been synthesized and subjected to triplet-sensitized photoisomerization. 2,3-Dicyanobenzobarrelene 5 gave two di-p-methane rearrangement products 7 and 8 and a [2p+2p]-cycloaddition product 9. However, 2,5-dicyanobenzobarrelene 6 formed a single di-p-m