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ChemInform Abstract: Remote Substituent Effects on Regioselectivity in the Pauson—Khand Reaction of 2-Substituted Norbornenes.

✍ Scribed by Peter Mayo; William Tam

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
32
Category
Article
ISSN
0931-7597

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1-Methyl-norbornene ester 9 and 1-methyl-2,3-diazabicyclo[2.2.1]heptene ester 10 were employed in intermolecular Pauson-Khand reactions with various terminal alkynes 11af to give the dimethyl 1-methyltricyclo[5.2.1.0 5,9 ]dec-7-en-6one 2,3-dicarboxylates 12 and 13, and diethyl 2,3-diaza-1methyltricy