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ChemInform Abstract: Control of the Regioselectivity in the Pauson—Khand Reaction of 7-Oxanorbornene Derivatives.

✍ Scribed by Odon Arjona; Aurelio G. Csaky; M. Carmen Murcia; Joaquin Plumet

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A Sub-Stoichiometri
ChemInform Abstract: A Sub-Stoichiometric Version of the Pauson—Khand Reaction.
✍ Thotapally Rajesh; Mariappan Periasamy 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

The title reaction is carried out with an alkyne-Co 2 (CO) 8 complex, generated in situ using sub-stoichiometric amounts of CoBr 2 and Zn at atmospheric pressure of carbon monoxide. Its coupling with the olefins (II) and (V) in the presence of CO completes the Pauson-Khand reaction providing the cyc