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Remote Control of Diastereoselectivity in Intramolecular Reactions of Chiral Allylsilanes

✍ Scribed by Judd, Weston R.; Ban, Sooho; Aubé, Jeffrey


Book ID
126293723
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
159 KB
Volume
128
Category
Article
ISSN
0002-7863

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The ester-allylsilanes ( 5) and ( 6) and the acid-allylsilane (7) react stereoselectively with m-CPBA; the major product from ( 5) and ( 7) was the y-lactone (4), whereas (6) failed to undergo lactonisation, the major product in this case was the P,wpoxy-silane (12).