✦ LIBER ✦

Relaxation of internal energy and collisional energy transfer

✍ Scribed by Wendell Forst

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 334 KB
Volume: 98
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)80090-6

No coin nor oath required. For personal study only.

✦ Synopsis

Using the exponcntll model for the collisional transition probability, it is sholtn that relawtion of average internal ensrg? is d medwe of bullxverage energy transfer K&3). This is a macroscopic property which is a complicated function of both time .md initial excitation .md 1s only distantly related to average energ transferred per collision ((ti)), a microscopic propert\ _

📜 SIMILAR VOLUMES

Infrared fluorescence and collisional en

Infrared fluorescence and collisional energy transfer parameters for vibrationally excited azulene*(So): dependence on internal energy (Evib)

✍ Michel J. Rossi; John R. Barker 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 519 KB

Gas-solid energy transfer: effect of int

Gas-solid energy transfer: effect of internal vibrational energy

✍ George Wolken Jr.; Jane Hylton McCreery 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 454 KB

Clasc~cal trajectories were run simulating the collision of a diatomic molecule with a sohd surface on a realistic potential energ+ surf.~cc. Previous model potentials have been gcnerslizcd to include I.Wicc dynzurucs in the solid surface snd, hence, the possibility of gas-solid energy tranGx. This

Measurements of collisional energy trans

Measurements of collisional energy transfer in unimolecular processes

✍ Robert G. Gilbert 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 388 KB

It is shown that the optimal means of tabulating collisional energy transfer parameters in gas-phase uni-and ter-molecular reactions is as the average downward energy transfer, rather than the total energy transferred or the collision efficiency.

Quantum effects in large molecule collis

Quantum effects in large molecule collisional energy transfer?

✍ Beatriz M. Toselli; John R. Barker 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 479 KB

Recently, Gilbert and Zare proposed that dynamical quantum effects might explain the poor performance ofclassical trajectory calculations in simulating the vibrational deactivation of excited azulene by the lighter noble gases. They proposed an experimental test: a comparison of 3He and 4He deactiva

The approximation of collisional energy

The approximation of collisional energy relaxation by imbedding diffusion processes

✍ Peter Clifford; Nicholas J.B. Green; Mark Bezant; Michael J. Pilling 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 880 KB

Intramolecular perturbations and collisi

Intramolecular perturbations and collisional energy transfer: Classical and quantum theory

✍ Robert Parson 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 319 KB

The effect of resonant intramolecular interactions upon vibrational energy transfer is studied using classical and quantum perturbation theory. It is shown that cancellations attributed previously to quantum interference may equally well be ascribed to a classical mechanism.