Measurements of collisional energy transfer in unimolecular processes
β Scribed by Robert G. Gilbert
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 388 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
It is shown that the optimal means of tabulating collisional energy transfer parameters in gas-phase uni-and ter-molecular reactions is as the average downward energy transfer, rather than the total energy transferred or the collision efficiency.
π SIMILAR VOLUMES
Using the exponcntll model for the collisional transition probability, it is sholtn that relawtion of average internal ensrg? is d medwe of bullxverage energy transfer K&3). This is a macroscopic property which is a complicated function of both time .md initial excitation .md 1s only distantly relat
## Abstract The application of modern theories of energy transfer to unimolecular reactions taking place at very high temperatures is discussed. It is shown that the efficiency of energy transfer for both reactantβreactant and reactantβinert diluent collisions may be substantially smaller than the