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Relaxation of excited methyl radicals produced in the flash photolysis of dimethyl mercury

✍ Scribed by A.B. Callear; H.E. Van den Bergh

Publisher: Elsevier Science
Year: 1970
Tongue: English
Weight: 268 KB
Volume: 5
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(70)80120-8

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✦ Synopsis

In the flash photolysis of Hg(CH3:2 it is shown that approsimntely 85% of the CH3 radicals are produced in escited vibrational states. Hate coefficients were measured for relaxation of the free radicals by He, Xr. 02, CH4. C2H6 and SFg. and it is suggested that the rate is controlled by the out-of-plane bending mode. The combination of CH? radicals showed no pressure dependence do\n to total pressures of 3 torr.

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