β Scribed by P.M. Rentzepis; R.P. Jones; Joshua Jortner
No coin nor oath required. For personal study only.
We report the observation of the ultrafast relaxation of a quasifree electron to the localized excess electron state in water. Quasifree electrons were generated by photoionization of aqueous ferrocyanide solutions by the fourth harmonic of a mode locked Nd 3Γ· laser. The rate of formation of the localized hydrated electron is ~ 2 psec.
π SIMILAR VOLUMES
The transtlon of excess electrons from the quasi-free to the locahzed state m subcnttcal and supercritrcaal ammonia vapour was observed m the density range from about 5 6 X IO" to 1 X 10-r g/cm3. In the same density range, the Kirk~ood correlatlon factorg as a measure of onentatmnal correlatron of a
## Abstract Isotropic Raman line broadening studies were carried out for the Cο£ΎO stretching mode of vibration in __N__,__N__βdimethylformamide and cyclohexanone molecules in solution. The broadening for the Raman band is explained on the basis of hydrodynamic, multipoleβmultipole, induction and dis
The free energy change of an electron transfer reaction in a polar solvent is rigorously analyzed within the framework of the dielectric continuum model. An appropriate expression for the electrostatic energy between the two product ions separated by R is derived. The present result does not support
The close-coupling equations describing the scattering of an electron by a rotating dipoie are solved numerically for a range of energies and a range of dipole moments. The results show no anomalies in the neighborhood of the critical dipole moment.