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Excess electrons as a probe for polar “fluid structure”

✍ Scribed by P. Krebs

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
357 KB
Volume
70
Category
Article
ISSN
0009-2614

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✦ Synopsis

The transtlon of excess electrons from the quasi-free to the locahzed state m subcnttcal and supercritrcaal ammonia vapour was observed m the density range from about 5 6 X IO" to 1 X 10-r g/cm3. In the same density range, the Kirk~ood correlatlon factorg as a measure of onentatmnal correlatron of ammoma molecules, has its strongest density dependence. From this fact and other experunental data on localized (solvated) electrons III sub-and super-cntual ammonia, It is concluded that the excess electron is a proper probe to study polar fluid structure

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