Methyl radical reactions with matrix molecules in glasses C2H50H, (CH20H)z, n-and i-C3H70H, n-and i-C4HsOH, n-and i-CSHIlOH, C~DSOH, and i-C:+D70D, and the reactions of C:2H5, C3H7, C4H9, C : ~H I ~ with methanol glasses have been studied. Alkyl radicals were produced by photolysis of diphenylamine-
โฆ LIBER โฆ
Time-resolved electron spin resonance with electron spin polarization (CIDEP) as a sensitive probe of degenerate electron exchange reactions
โ Scribed by S. Basu; K.A. McLauchlan; A.J.D. Ritchie
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 323 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
It is shown that the o~currente of electron-exchange processes produces a dislinctive effect in the time-resolved electron spin resonance spectra of spin-polarized radicals observed in the continuous presence of a micro\vave field. The effects observed are consistent with a theory based upon the Bloch equations.
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1978
๐
John Wiley and Sons
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โ 503 KB