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Relative reactivities of the pyridine and benzimidazole systems in the chichibabin reaction

✍ Scribed by A. F. Pozharskii; V. V. Kuz'menko; Yu. V. Kolodyazhnyi; A. M. Simonov


Book ID
112441365
Publisher
Springer US
Year
1972
Tongue
English
Weight
1019 KB
Volume
8
Category
Article
ISSN
0009-3122

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Several aspects of the unusual behavior of C 6 C 2 aldehydes and amines during the formation of pyridiniums in analogy with the historical Chichibabin pyridine synthesis are clarified in this Letter. Interesting biosynthetic consequences are also discussed within two classes of polycyclic alkaloids