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Relative Reactivities of the Olefinic and Cyano Links of Acrylonitrile in the Diels–Alder Reaction

✍ Scribed by JANZ, G. J.; DUNCAN, N. E.

Book ID
109573502
Publisher
Nature Publishing Group
Year
1953
Tongue
English
Weight
115 KB
Volume
171
Category
Article
ISSN
0028-0836

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✍ Rubén Sanabria; Rafael Herrera; Raúl Aguilar; Carlos González-Romero; Hugo A. Ji 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 German ⚖ 435 KB

## Abstract The reactivity and selectivity of the the captodative olefins 1‐acylvinyl benzoates **1a**–**1f** and **3a** as heterodienes in hetero__‐Diels__–__Alder__ reactions in the presence of electron‐rich dienophiles is described. Heterodienes **1** undergo regioselective cycloaddition with th