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ChemInform Abstract: Reactivity of N-Phenyl-1-aza-2-cyano-1,3-butadienes in the Diels-Alder Reaction.

✍ Scribed by N. J. SISTI; I. A. MOTORINA; M.-E. TRAN HUU DAU; C. RICHE; F. W. FOWLER; D. S. GRIERSON

Book ID: 112037995
Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 27
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199639165

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✍ Sisti, Nicholas J.; Motorina, Irina A.; Tran Huu Dau, Marie-Elise; Riche, Claude 📂 Article 📅 1996 🏛 American Chemical Society 🌐 English ⚖ 435 KB

ChemInform Abstract: Intramolecular Diel

ChemInform Abstract: Intramolecular Diels-Alder Reaction of 2-Cyano-1-aza-1,3-butadienes.

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Intramolecular Diels−Alder Reaction of 2-Cyano-1-aza-1,3-butadienes

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ChemInform Abstract: N-Phenyl-1-aza-2-cyano-1,3-butadienes: An Intramolecular Hetero Diels—Alder Strategy for the Construction of 1,4-Benzodiazepines.

✍ C. GOULAOUIC-DUBOIS; D. R. ADAMS; N. J. SISTI; F. W. FOWLER; D. S. GRIERSON 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 3 views

N-Phenyl-1-aza-2-cyano-1, 3-butadienes:

N-Phenyl-1-aza-2-cyano-1, 3-butadienes: An intramolecular hetero Diels-Alder strategy for the construction of 1, 4-benzodiazepines

✍ Catherine Goulaouic-Dubois; David R. Adams; Nicholas J. Sisti; Frank W. Fowler; 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 189 KB

A new approach to the construction of tricyclic 1,4-benzodiazepines has been developed, based upon the intramolecular Diels-Alder (IMDA)reaction of 2-cyano-l-azadienes. This study revealed the difficulties inherent to the direct transformation of imine-amide 2 to azadiene 3, but demonstrated the eff