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Relative kinetics of the radical telomerization of vinyl chloride with carbon tetrabromide and dichlorodibromomethane

✍ Scribed by T. T. Vasil'eva; V. A. Koche-tkova; V. I. Dostovalova; B. V. Nelyubin


Book ID
112444914
Publisher
Springer
Year
1989
Tongue
English
Weight
405 KB
Volume
38
Category
Article
ISSN
1573-9171

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Kinetics and mechanism of the reaction o
✍ Jong-Yoon Park; Michael C. Heaven; David Gutman πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 English βš– 501 KB

The kinetics and mechanism of the gaseous reaction of vinyl radicals with molecular oxygen have been studied at 296 K. The products formed are HCO and H2C0. The rate constant is 1.0 X 10-r' cm3 molecule-' s-\* and is independent of pressure between 0.4 and 4 Torr.