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Radical-type addition of benzyl bromide to vinyl chloride: the kinetics and activation energy of the process

✍ Scribed by T. T. Vasil'eva; S. I. Gapusenko; A. B. Terent'ev; V. V. Pinyaskin; I. V. Stankevich; A. L. Chistyakov; E. I. Mysov


Book ID
112387252
Publisher
Springer
Year
1993
Tongue
English
Weight
355 KB
Volume
42
Category
Article
ISSN
1573-9171

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Kinetics of the I2-catalyzed isomerizati
✍ Ze'ev B. Alfassi; David M. Golden; Sidney W. Benson πŸ“‚ Article πŸ“… 1973 πŸ› John Wiley and Sons 🌐 English βš– 664 KB

## Abstract The I~2~‐catalyzed isomerization of allyl chloride to __cis__‐ and __trans__‐ l‐chloro‐l‐propene was measured in a static system in the temperature range 225–329Β°C. Propylene was found as a side product, mainly at the lower temperatures. The rate constant for an abstraction of a hydroge