Kinetics and mechanism of the addition of the phthalimid-n-oxyl radical to the double bond of vinyl compounds
โ Scribed by I. A. Opeida; M. A. Kompanets; O. V. Kushch; A. G. Matvienko
- Publisher
- Springer
- Year
- 2010
- Tongue
- English
- Weight
- 108 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0040-5760
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The aqueous cleavage of N-(2-bromoethyl)phthalimide (NBEPH), N-(3-bromopropyl)phth&mide (NBPPH), and N-carbethoxyphthalimide (NCPH) have been studied within the [OH] range of 5 x 10 M to 2 x 10.' M, pH range of 8.82 to 10.62 and 8.06 to 8.66, respective1y:The observed pseudo-first-order rate consta
The kinetics and mechanism of the gaseous reaction of vinyl radicals with molecular oxygen have been studied at 296 K. The products formed are HCO and H2C0. The rate constant is 1.0 X 10-r' cm3 molecule-' s-\* and is independent of pressure between 0.4 and 4 Torr.